Oxidation of Tyrosine

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The following references detect the transient tyrosyl radical.

KMnO4

The Electron Spin Resonance Spectrum of the Tyrosyl Radical
Roger C. Sealy, Laura Harman, Paul R. West, and Ronald P. Mason.
Journal of the American Chemical Society, 1985, 107(12), pp. 3401-3406.
here
Sealy, 1985


HRP/H2O2

The Fate of the Oxidizing Tyrosyl Radical in the Presence of Glutathione and Ascorbate: IMPLICATIONS FOR THE RADICAL SINK HYPOTHESIS
Bradley E. Sturgeon, Herbert J. Sipe, Jr., David P. Barr, Jean T. Corbett, Jose G. Martinez, and Ronald P. Mason.
Journal of Biological Chemistry, 1998, 273(46), pp. 30116-30121.
here
Sturgeon,1998

HRP/H2O2/NO

Tyrosine iminoxyl radical formation from tyrosyl radical/nitric oxide and nitrosotyrosine.
Sturgeon BE, Glover RE, Chen YR, Burka LT, and Mason RP.
Journal of Biological Chemistry, 2001, 276(49), pp. 45516-45521.
here
Sturgeon, 2001

Other

Media:Bi963168z.pdf