Ch7 Lec 3

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(4/24/20, bes)

Greetings,

Congratulations for making it thru the week! Only 1.5 week left...or 5 more class periods...and one more lab.

EXAM 3 Announcement: Friday, May 1st (1 week from today) we will have Exam 3 (Ch 6 and 7) via WA. Just like last time, the WA-exam will be timed and available at 8 am. You may take the exam at anytime during the day, but once you open the assignment you have...60 mins...plus a BONUS 15 mins...75 min total. I want all exams completed by 5 pm, so you should start before 3:45 pm. If you know of a valid conflict please email to discuss.

I will be sending out an email when i get the Ch 7 WA completed...soon. It will not be due until next week Thurs 5 pm.

...continuing with Chapter 7...

Sec 7.4/7.5: The Dual Nature of the Electron and Quantum Mechanics

Read/skim these sections.

As i noted when discussing the emission spectrum of the H-atom, there were many "molecular-type" experiments that were done that classical mechanics (standard physics) could not explain. Hence the rise of quantum mechanics (QM). The following video is a nice explanation of the "double-slit" experiment that highlighted the "dual nature" of the electron...and introduces you to a few QM concepts.

Dr Quantum Wave particle duality...and the double slit experiment

Sec 7.6: Quantum Numbers

Let's go back to a figure presented in lecture 2...

Balmer energy levels.png

This H-atom emission spectrum figure is derived from lots of experimental data and mathematical interpretation. The take home point is that electrons in an atom exist in particular energy levels/states. As stated, the quantum world follows a different set of laws than our macroscopic world we see all around us. I can make an analogy to a building...the quantum energy levels are kind of like the floors of a multi-story building like CSB...CSB has floors 1, 2, and 3. A person (or electron) can exist on any floor and at anytime we can count the number of people on any given floor...the key point to this is that every person is on "a" floor...1, 2, or 3 and these are the only options! sure you might find someone on the stairs going up or down, but the time spent on the stairs is minimal compared to being on a particular floor. The floors represent "levels or states." Note also that in order to go from one floor to another this requires energy...1st --> 2nd requires input of energy; 3rd --> 2nd releases energy, etc.

Okay, so now that we know that electrons exist in well defined energy levels (or energy states...same thing), we need a way of keeping track of these levels. The values shown in the above figure, n = 2, then 3, 4, 5, 6...and called the "principal" number...or principal quantum number.

Sec 7.7: Atomic Orbitals

Sec 7.8: Electron Configuration

Sec 7.9: The Building-Up Principle