Difference between revisions of "Free Radical Generation"
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===2. Cerium (IV)=== | ===2. Cerium (IV)=== | ||
| + | For Cerium Free Radicals: | ||
| + | 100 mL solution of 2 mM HPA and 100 mL solution of Ce (IV). | ||
| + | For 100 mL of 2 mM HPA: | ||
| + | Weigh out 30.4mg of HPA | ||
| + | Add it into 100 mL DI water | ||
| + | For 100 mL of 2 mM Ce (IV) | ||
| + | Weigh out 109.6 mg of Ammonium Cerium Nitrate | ||
| + | Add that to 2.5 mL of 18M sulfuric acid | ||
| + | Add that solution to 97.5 mL of DI water | ||
===3. Fenton Chemistry=== | ===3. Fenton Chemistry=== | ||
Revision as of 21:13, 14 April 2016
The 1-electron oxidation of a phenol can be accomplished via chemical or enzymatic means.
Chemical Means
1) KMnO4
2. Cerium (IV)
For Cerium Free Radicals: 100 mL solution of 2 mM HPA and 100 mL solution of Ce (IV). For 100 mL of 2 mM HPA: Weigh out 30.4mg of HPA Add it into 100 mL DI water For 100 mL of 2 mM Ce (IV) Weigh out 109.6 mg of Ammonium Cerium Nitrate Add that to 2.5 mL of 18M sulfuric acid Add that solution to 97.5 mL of DI water