Difference between revisions of "Carley Folluo Chem430 F16"

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==Proposed Research Project==
 
==Proposed Research Project==
===EPR Analysis of Mn2+ Geometry===
+
===EPR Analysis of Neutron Radiated Teeth===
  
 
===General Information===
 
===General Information===
 
:Advisor: Brad Sturgeon
 
:Advisor: Brad Sturgeon
 
:Other research student collaborators: Amanda Hanks (Class of 2015)
 
:Other research student collaborators: Amanda Hanks (Class of 2015)
:Other Research Collaborators:  
+
:Other Research Collaborators: Dr. Fasano
  
 
===Proposal===
 
===Proposal===
The goal of this project is to develop an Electron Paramagnetic Resonance (EPR) teaching method through the execution of various instructional experiments. Samples studied include Mn2+ impurities in MgO, CaO, and SrO complexes and TEMPO in aqueous solution. The MgO, CaO, and SrO complexes are obtained by oxidizing Mg, Ca, and Sr metal. The goal of the instructional experiments is to offer a student an in-depth understanding of how electron spin, d-orbital filling, molecular geometry, nuclear spin, and crystal field affect an EPR spectrum.
+
The goal of this project is to develop a method to detect radicals in the crystal structure of teeth created by neutron radiation. Whole human teeth have been obtained from a local dentist, and will be placed in the beam of the neutron generator. After the teeth have been irradiated, counts will be taken with a high purity germanium detector in order to determine the activity of the sample.  After the radionuclides have decayed, the teeth will be ground for analysis by electron paramagnetic resonance.  
  
 
===Instruments to be used===
 
===Instruments to be used===
Electron Paramagnetic Resonance (EPR)
+
:Electron Paramagnetic Resonance (EPR)
 +
:Neutron Generator
  
 
===References (2 minimum)===
 
===References (2 minimum)===

Revision as of 21:27, 5 September 2016

Chemistry Research 430

Fall 2016
Carley Folluo
Senior Chemistry Major

Research Times

Monday 1-5 PM

Overflow: Tues/Wed 3-5 PM
CHEM 430-01 = 0.25 credit = 4 hours per week.

Proposed Research Project

EPR Analysis of Neutron Radiated Teeth

General Information

Advisor: Brad Sturgeon
Other research student collaborators: Amanda Hanks (Class of 2015)
Other Research Collaborators: Dr. Fasano

Proposal

The goal of this project is to develop a method to detect radicals in the crystal structure of teeth created by neutron radiation. Whole human teeth have been obtained from a local dentist, and will be placed in the beam of the neutron generator. After the teeth have been irradiated, counts will be taken with a high purity germanium detector in order to determine the activity of the sample. After the radionuclides have decayed, the teeth will be ground for analysis by electron paramagnetic resonance.

Instruments to be used

Electron Paramagnetic Resonance (EPR)
Neutron Generator

References (2 minimum)

Randall, D. W., Sturgeon, B. E., Ball, J. A., Lorigan, G. A., Chan, M. K., Klein, M. P., … Britt, R. D. (1995). 55Mn ESE-ENDOR of a Mixed Valence Mn(III)Mn(IV) Complex: Comparison with the Mn Cluster of the Photosynthetic Oxygen-Evolving Complex. Journal of the American Chemical Society, 117(47), 11780–11789.

Sturgeon, B. E., Ball, J. A., Randall, D. W., & Britt, R. D. (1994). 55Mn Electron Spin Echo ENDOR of Mn2+ Complexes. The Journal of Physical Chemistry, 98(49), 12871–12883.

Research pledge

I, Carley Folluo, have read the Chem/Bioc 430 course syllabus and understand the general structure and expectations of the research program. The above material was prepared after consultation, and in conjunction with my research advisor.