Difference between revisions of "PChem322 s22 w1"

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...now on to PChem...
 
...now on to PChem...
:3) It is time to start reading the text. Please note, that reading any science textbook is NOT like reading other documents. The information is presented in a very dense way...this means that there is a lot of scientific language that needs to be read multiple times in order to make sense. There are parts of your textbook that when i read them, i ask myself what was the author thinking be including this...crap!
+
:3) It is time to start reading the text. Please note, that reading any science textbook is NOT like reading other documents. The information is presented in a very dense way...this means that there is a lot of scientific language that needs to be read multiple times in order to make sense. The Quantum textbook (Chem 322) is more clearly written than the Thermodynamic textbook (Chem 312). The authors, Engel and Reid initially published a single textbook containing both sections called "Physical Chemistry" (literally the two books bound into one). In addition to the single textbook, the publisher always printed the two sections separately; the 4th edition of this textbook is only printed as separate sections...no more single textbook containing both. As you will note, the Quantum textbook is written by Engel alone. I meet this author and had lunch with him at the 2017 Denver ACS meeting: great guy, has essentially retired and works mainly on gardening and editing his textbooks.
::- Let's start by reviewing the MATH ESSENTIALS 1 section (Page 1-3). As you might already know, PChem uses the language of mathematics to organize its contents. Calc 1 and Calc 2 are prerequisites for this course (although they are sometimes waived). Yes we will be taking derivatives and later integrals, but more importantly, you need to be comfortable with math in general. Math is a tool and by the way, you cannot hate a tool, as in..."i just don't like hammers." Although you may have had a bad experience with math in the past, i will present math in a way that you will find it helpful...like how a hammer is really good at driving nails!  
+
 
 +
::- Let's start by reviewing the MATH ESSENTIALS 1 section (Page 1-3). As you might already know, PChem uses the language of mathematics to organize its contents. Calc 1 and Calc 2 are prerequisites for this course (although they are sometimes waived). Yes we will be taking derivatives and integrals, but more importantly, you need to be comfortable with math in general. Math is a tool and by the way, you cannot hate a tool, as in..."i just don't like hammers." Although you may have had a bad experience with math in the past, i will present math in a way that you will find it helpful...like how a hammer is really good at driving nails!  
 
:::*Please review this section (pages 1-3) now. In your notes, please write down all of the units listed in Table ME1.2 and indicate whether you are comfortable with these units (check) or not (???).
 
:::*Please review this section (pages 1-3) now. In your notes, please write down all of the units listed in Table ME1.2 and indicate whether you are comfortable with these units (check) or not (???).
 
:::*In Section ME1.2...sig figs...this is something you should know well!
 
:::*In Section ME1.2...sig figs...this is something you should know well!
:::*In section ME1.3...they suggest that writing out all of your work is strongly suggested since it allows you to go back and correct any errors. Please work this problem in your notes as if you were going to answer this question on an exam (ie. Show your work)...we can use Mathematica(R) and/or Excel(R) at a later time to solve such problems.
+
:::*In section ME1.3...they suggest that writing out all of your work is strongly suggested since it allows you to go back and correct any errors. Please work this problem in your notes as if you were going to answer this question on an exam (ie. Show your work). Now use Excel to reproduce the spreadsheet shown at the bottom of page 3. At a later time we will use Mathematica to solve such problems.
 
 
::- Let's continue reading sections 1.1-1.3. You may not be able to read all of this in the 50 mins...i.e. now, so consider this homework. Remember when i said the author sometimes writes...crap...well the beginning of section 1.2 (page p7-8) is crap...but i understand why he added this section...math is a powerful tool. This is not a good example of how PChem will be presented. Much of the information is qualitative and we will begin our quantitative work on Friday.
 
 
 
END.
 
 
 
 
 
<!--
 
 
 
===Chapter 1: From Classical to Quantum Mechanics===
 
====Intro, Sec 1.1, Sec 1.2====
 
Read
 
 
 
====Sec 1.3 Blackbody Radiation====
 
:[https://en.wikipedia.org/wiki/Planck's_law Plank's Law (Wikipedia)]
 
 
 
:- All objects are essentially "hot" (considering the concept of absolute zero).
 
:- All (hot) objects radiate light (electromagnetic radiation).
 
:- The wavelength/frequency of the light emitted from a (hot) object is related to the temperature of the object.
 
:- We can make a graph of wavelength (''λ'') or frequency (''ν'') as a function of temp (T), but at any given temperature light emitted has a range of ''λ'' or ''ν''. So instead we develop some expressions using the term spectral density (''ρ'' - rho).
 
 
 
[[File:Screen Shot 2021-01-27 at 9.18.22 AM.png|400px]]
 
-->
 
<!--
 
==Thurs, Jan 28, 2021==
 
Meet in CSB 378
 
 
 
'''''PLEASE make an entry in your lab notebook'''''
 
===Activity 1: Mathematica===
 
:- Basic Plot statement
 
::* Plot[x^2, {x, 0, 10}]
 
:- Plotting 2 function on one graph
 
::* Plot[{x^2, X^3}, {x, 0, 10}]
 
:- "Manipulate" a Plot
 
::* Manipulate[Plot[{a*x^2, a*x^3}, {x, 0, 10}], {a, 1, 2}] ...with y-axis range defined
 
::* Manipulate[Plot[{a*x^2, a*x^3}, {x, 0, 10}, PlotRange -> {0, 2000}], {a, 1, 2}]
 
  
:'''Challenge''': Reproduce the Figure 1.2 above for Plank's Blackbody Radiation (spectral density vs frequency)
+
::- The next pages in the textbook are an additional 3 MATH ESSENTIALS sections (2-4). These will be VERY handy in the future as a place to look up derivatives and integrals, but for now let's skip these sections.  
::- First try and use the "Manipulate" function, then do the plot of 5 functions.
 
::- See here for the function (slightly different than book) -- [https://en.wikipedia.org/wiki/Planck's_law Plank's Law (Wikipedia)]
 
-->
 
<!--
 
===Activity 2:Emission Spectra===
 
:Demonstration
 
:[[Media:HW2_Emission.pdf|Excel worksheet]]
 
  
===Activity 3===
+
::- The first Chapter of the textbook makes a strong case related to why we need quantum mechanics and not just classical mechanics. There are 4 experiments done in modern times (last 100 years) that have shown that classical mechanics cannot explain the experimental outcomes, the experiments are named:
:'''''NOVA: Beyond the Elements'''''
+
:::1) Blackbody Radiation (Sec 1.3)
:Time 5:00 pm
+
:::2) The Photoelectric Effect (Sec 1.4)
 +
:::3) Particle-Wave Duality
 +
::::- Particles acting as waves (Sec 1.5)
 +
::::- Waves acting at particles (Sec 1.6)
 +
:::4) Emission Spectra (Sec 1.7)
  
==Friday, Jan 29, 2021==
+
::For now, i would like for you to read Sec 1.1 and 1.2, but get ready to do some math shortly.
====Sec 1.3 Blackbody Radiation - lab REVIEW====
 
====Sec 1.7 Emission Spectra - lab REVIEW====
 
  
====Sec 1.4 The Photoelectric Effect====
+
END
:[[Media:HW1_Photoelectric.pdf|Photoelectric Effect worksheet]]
 
:[[File:Screen Shot 2021-01-29 at 9.51.50 AM.png|300px]]
 
-->
 

Revision as of 16:19, 12 January 2022

...return to Chem 322 - home

Weds, Jan 12, 2022

Announcements

0) Nearly all of you in PChem II are also in PChem I. There are some introductory topics that I want to share with all PChem students, so there is some duplication of assignments at the beginning of Chem 312 and 322. Only complete items below that are new to you.
1) If you have not done so, please review the syllabus linked here.
2) Question: Is your computer up to speed? During this course, we will be using software such as Excel, WORD, Igor, Mathematica etc. Although there are computers available on campus (specifically in CSB 373), it is most convenient for you to install this software on your computer (laptop preferred). It may be the case that a "ChromeBook" or other cloud-based OS device may have sufficed in the past, it will not work in PChem...but computers will be available in CSB 373. Please see/email me with any questions.

Class Assignments

1) I would like for you to watch the following video that discusses being proactive vs. reactive. I have found that PChem students who are most successful would describe themselves as being proactive. I think you will agree that we should all shoot for being proactive in our lives, but this is a clear skill that even I am working on improving. The video moves quickly, so I suggest you just listen the first time, then consider coming back to this view it again at another time. We will discuss this more in class when we meet in person.
Proactive vs. Reactive
2) If the above material is interesting, consider learning more about Stephen Covey or how to use the Franklin Planner.
Steven Covey - Wikipedia (optional)
Franklin Covey - Wikipedia (optional)
Franklin Planner - Wikipedia (optional)
Weekly Planner example page (optional)

...now on to PChem...

3) It is time to start reading the text. Please note, that reading any science textbook is NOT like reading other documents. The information is presented in a very dense way...this means that there is a lot of scientific language that needs to be read multiple times in order to make sense. The Quantum textbook (Chem 322) is more clearly written than the Thermodynamic textbook (Chem 312). The authors, Engel and Reid initially published a single textbook containing both sections called "Physical Chemistry" (literally the two books bound into one). In addition to the single textbook, the publisher always printed the two sections separately; the 4th edition of this textbook is only printed as separate sections...no more single textbook containing both. As you will note, the Quantum textbook is written by Engel alone. I meet this author and had lunch with him at the 2017 Denver ACS meeting: great guy, has essentially retired and works mainly on gardening and editing his textbooks.
- Let's start by reviewing the MATH ESSENTIALS 1 section (Page 1-3). As you might already know, PChem uses the language of mathematics to organize its contents. Calc 1 and Calc 2 are prerequisites for this course (although they are sometimes waived). Yes we will be taking derivatives and integrals, but more importantly, you need to be comfortable with math in general. Math is a tool and by the way, you cannot hate a tool, as in..."i just don't like hammers." Although you may have had a bad experience with math in the past, i will present math in a way that you will find it helpful...like how a hammer is really good at driving nails!
  • Please review this section (pages 1-3) now. In your notes, please write down all of the units listed in Table ME1.2 and indicate whether you are comfortable with these units (check) or not (???).
  • In Section ME1.2...sig figs...this is something you should know well!
  • In section ME1.3...they suggest that writing out all of your work is strongly suggested since it allows you to go back and correct any errors. Please work this problem in your notes as if you were going to answer this question on an exam (ie. Show your work). Now use Excel to reproduce the spreadsheet shown at the bottom of page 3. At a later time we will use Mathematica to solve such problems.
- The next pages in the textbook are an additional 3 MATH ESSENTIALS sections (2-4). These will be VERY handy in the future as a place to look up derivatives and integrals, but for now let's skip these sections.
- The first Chapter of the textbook makes a strong case related to why we need quantum mechanics and not just classical mechanics. There are 4 experiments done in modern times (last 100 years) that have shown that classical mechanics cannot explain the experimental outcomes, the experiments are named:
1) Blackbody Radiation (Sec 1.3)
2) The Photoelectric Effect (Sec 1.4)
3) Particle-Wave Duality
- Particles acting as waves (Sec 1.5)
- Waves acting at particles (Sec 1.6)
4) Emission Spectra (Sec 1.7)
For now, i would like for you to read Sec 1.1 and 1.2, but get ready to do some math shortly.

END