Difference between revisions of "ESR Lab Activity"
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| Line 10: | Line 10: | ||
{| class="wikitable" | {| class="wikitable" | ||
||Name | ||Name | ||
| + | ||SDS | ||
||Molar Mass | ||Molar Mass | ||
||Sigma Product Number | ||Sigma Product Number | ||
| Line 15: | Line 16: | ||
|- | |- | ||
||Hydroquinone | ||Hydroquinone | ||
| + | ||SDS | ||
||110.11 g/mol | ||110.11 g/mol | ||
||[http://www.sigmaaldrich.com/catalog/product/sial/h9003?lang=en®ion=US H9003] | ||[http://www.sigmaaldrich.com/catalog/product/sial/h9003?lang=en®ion=US H9003] | ||
| Line 20: | Line 22: | ||
|- | |- | ||
||Methylhydroquinone | ||Methylhydroquinone | ||
| + | ||[[Media:Methylhydroquinone.pdf|SDS]] | ||
||124.14 g/mol | ||124.14 g/mol | ||
||[http://www.sigmaaldrich.com/catalog/product/aldrich/112968?lang=en®ion=US 112968] | ||[http://www.sigmaaldrich.com/catalog/product/aldrich/112968?lang=en®ion=US 112968] | ||
| Line 25: | Line 28: | ||
|- | |- | ||
||2,3-dimethylhydroquinone | ||2,3-dimethylhydroquinone | ||
| + | ||SDS | ||
||138.16 g/mol | ||138.16 g/mol | ||
||[http://www.sigmaaldrich.com/catalog/product/aldrich/300756?lang=en®ion=US 300756] | ||[http://www.sigmaaldrich.com/catalog/product/aldrich/300756?lang=en®ion=US 300756] | ||
Revision as of 19:59, 21 April 2016
Introduction
We are going to collect an ESR spectrum from a series of substituted hydroquinones.
- A=Hydroquinone (110.11 g/mol)
- B=methylhydroquinone (124.14 g/mol)
- C=2,3-dimethylhydroquinone (138.16 g/mol)
| Name | SDS | Molar Mass | Sigma Product Number | Cost |
| Hydroquinone | SDS | 110.11 g/mol | H9003 | 22.90 / 100g |
| Methylhydroquinone | SDS | 124.14 g/mol | 112968 | 59.20 / 250g |
| 2,3-dimethylhydroquinone | SDS | 138.16 g/mol | 300756 | 118.00 / 5g |
Experimental
Beaker Method
- Solution A: 1 M NaOH; 1 gram NaOH (39.997 g/mol) into 25 mL EtOH.
- Solution B: 1 M hydroquinone solution.
- Procedure: To 2 ml of 1 M hydroquinone solution add 2-3 drops of solution A. A color change will indicate the reaction has occurred. Quickly transfer colored sample to ESR sample tube, place in ESR spectrometer, tune, and collected data.
Flow Method
- Solution A: 0.05 M NaOH; 0.05 grams NaOH (39.997 g/mol) into 25 ml EtOH.
- Solution B: 1 M hydroquinone solution.
- Procedure: Prepare two 60 ml syringes, 1 with solution A and 1 with solution B.
- Degas the syringe that contains solution B
- Attach to double syringe drive
- Turn on double syringe drive
- Collect data